Search results for "Natural water"

Profiling Suspensions in Natural Water by a Simplified Dynamic Light Scattering Procedure and Sedimentation

2015

Abstract A coherent light scattering experiment was carried out. The samples were aqueous natural water suspensions picked from the same river. While sedimentation occurred in the samples, they were subjected to a dynamic light scattering (DLS) experiment and the time series was recorded at certain time intervals. For each recording, a program written for this purpose, performing at least square minimisation, computed the average diameter of the particles in suspension. The variation of the average diameter in time indicates the dominant type of suspensions in water.

Determination of mercury at picogram level in natural waters with inductively coupled plasma mass spectrometry by using 3D printed metal scavengers

2019

The determination of ultra-trace concentrations of Hg in natural water samples via preconcentration using 3D printed metal scavenger technique followed by inductively coupled plasma mass spectrometry (ICP-MS) was developed. The determination of Hg in certified reference material ERM-CA615 (groundwater) was performed with high accuracy and precision resulting in recovery of 100 ± 3% and RSD <2.5%, respectively. Selective laser sintering (SLS) 3D printing was used to fabricate the scavengers using a mixture of polyamide-12 powder with thiol-functionalized silica. The preconcentration procedure is based on the adsorption of Hg on the scavenger and followed by elution of the preconcentrated Hg …

Response by macrozoobenthos biomass to water level regulation in some Finnish lake littoral zones

1994

The relationship of the macrozoobenthos biomass in the littoral area to the yearly fluctuation in water level and the characteristics of the area or lake are studied using data collected from sheltered bays in regulated and natural waters. Most of the lakes were clear and oligotrophic. The benthos biomass at all depths in the littoral decreased with increased water level fluctuation, provided that the transparency of the water was uniform.

Transportation of complexing agents released by pulp and paper industry: A Finnish lake case

1996

Complexing agents (EDTA, DTPA) are used to bind metal ions in pulp and paper industry. Their role will increase significantly when the total chlorine free (TCF) processes will be applied to a larger extent. EDTA and DTPA were analysed in the waters from the southern part of the Lake Saimaa (SE Finland) influenced by the effluents of three pulp and paper mills. The samples were collected at different distances from the points of emission. The results of analyses suggest that EDTA can persist in lake water and is able to propagate for considerable distances, while DTPA can be detected only in the near surroundings of the site of release. Some EDTA was found even in the sampling points that we…

Sicilian bottled natural waters: Major and trace inorganic components

2013

Sixteen bottled waters of various Sicilian brands, 11 natural mineral waters and five normal drinking waters, were analyzed for major and trace inorganic components by ion chromatography (IC) and inductively coupled plasma-mass spectrometry (ICP-MS), respectively. The bottled waters represent a variety of water types with significantly different compositions in terms of salinity, major components and trace elements. Chemically, they range from Ca–HCO3 and Ca–SO4 to Na–HCO3 types. Total dissolved solids ranges from 54 to 433 mg/L, total hardness from 25 to 238 mg/L CaCO3, and measured Na content from 5.7 to 57 mg/L. According to total dissolved ions, all the bottled waters were classified as…

Monitoring of the pesticide levels in natural waters of the Valencia Community (Spain)

1994

Colorimetric method for the determination of vanadium with tannic acid in water and oils

1994

A new spectrophotometric method was developed to determine vanadium using tannic acid as a complexing reagent to form a coloured reaction product which can easily be extracted by 1-pentanol in the presence of cetylpyridinium. The developed method can successfully be applied to determine trace levels of 10 ng/ml of vanadium in natural waters without any preconcentration step. It can also determine less than 1 mg/kg of vanadium in edible oils and petroleum products.

Multi-pumping mechanised determination of selenium in natural waters by light emitting diode (LED) spectrometry

2009

It has been developed a fully mechanised procedure for the determination of selenium in waters employing a LED based spectrometer and solenoid multi-pumps as solution propelling devices. The proposed method is based on the reaction of selenium with potassium iodide in an acidic medium to liberate iodine, which oxidizes Variamine Blue to form a violet-colour species which absorb at 530 nm. The system was mechanised using the multicommutation process and a stopped flow strategy in the final step reaction. The analytical curve was linear between 0.010 and 0.500 mg L-1, with an equation ΔA = 0.501 (± 0.004) C and r = 0.999. The limit of detection (3σ/S) obtained for the proposed method was 0.00…

Speciation of chromium in natural waters by micropumping multicommutated light emitting diode photometry.

2007

Abstract A simple and sensitive multicommutated flow procedure, implemented by employing a homemade light emitting diode (LED) based photometer, has been developed for the determination of chromium (VI) and total chromium in water. The flow system comprised a set of four solenoid micro-pumps, which were assembled to work as fluid propelling and as commutating devices. The core of the detection unit comprised a green LED source, a photodiode and a homemade flow cell of 100 mm length and 2 mm inner diameter. The photometric procedure for the speciation of chromium in natural waters was based on the reaction of Cr (VI) with 1,5-diphenylcarbazide. Cr (III) was previously oxidized to Cr (VI) and…

Dissolved CO2 in natural waters: development of an automated monitoring system and first application to Stromboli volcano (Italy)

2011

The study of geochemical parameters applied to natural systems has provided improved knowledge of geochemical mechanisms of gas/rock dissolution in natural waters that are linked to gas-water and/or water-rock interaction processes. Here we present the results of our studies focused on the development of an automated monitoring system for measuring the amount of dissolved CO2 in natural waters. The system is based on the principle of a dynamic equilibrium between water and the air as the host gas. The PCO2 measurements were carried out every four hours, and the equilibration time was around 20 minutes. Moreover, application to the thermal aquifer of Stromboli volcano during the 2009-2010 pe…